Same as PayPal. The gold standard for mega-sized orders where you want absolute security is still Western Union or any other form of money order. e.g. you can get a money order from most any grocery store, bank, or at the post office.
Moneybookers is WAY more popular in EU than PayPal is, so if you're going to be dealing with a lot of customers and some will be international, get both payment gateways. You'll eventually be happy you set that up.